So which is better? To eat a ton of whey, or a ton of Casein? I would think that the Casein would be better because it is digested slower, and gives you a more sustained release of protein into your bloodstream.
Wrong.
Remember this rule - you need fast protein and slow carbs.
Whey protein is better during the day (and especially post workout) as it gets into your system faster and prevents catabolism. You should be ingesting fast digesting protein (such as whey isolate) into your body at least every three hours to prevent catabolism and maintain anabolism (two hours for very skinny ectomorphs).
The only time you should ingest casein is just before bedtime - the time-released nature of the protein will prevent catabolism while you sleep and allows the body to recover at the same time over an extended period.
Casein isn't as good as whey isolate because the amino acid ratio isn't as good or diverse. Whey is a "perfect" protein source as it contains 100% of all essential amino acids and 90% of all powder ingested gets absorbed by the body compared to only about 70% for casein. In other words, for every 10 grams of caein you take in, the body will only use 7 grams for muscle building purposes. The rest will get wasted.
The complete opposite is tru for carbs - you need slow-releasing carbs (complex carbs) as the rapid insulin spike you get from fast-released carbs (simple carbs) isn't good for the body. Slow releasing carbs are less likely to promote fat gain.
Hope this helps