Well - lets see.
I start off at 6:30am, get ready, 7:15am, have breakfast with the family, and by 7:40am, I take my 5 year old daughter to kindergarten, (15 minutes away) so usually at work by 8:30am.
First, I go through business of the day at work, and a ton of emails, and a myriad of other items. I log in when I can, but sometimes it is busy, so I don't have much time.
So back to the question - when I log in.
Check the current threads, see which report to moderator lists I need to clean up, go through some PMs, and so on, when I have time.
That is, after I had my cup of coffee.