General rule of thumb in lifting is to do the heavier compound exercises first, when full attention and more energy is invested in them.
There is more demand on the body when doing heavier compound movement like squats, DL's,cleans, etc, because they help set up the metabolism for increases in strength and growth. A high functioning metabolism can release natural body homones, and other related chemicals, into the blood stream and into each cell. A very import element for quicker progressive growth and strength. Doing curls or lateral raises go far in not even coming close to the benefit of heavier compound movements.
With a full body workout, most guy's do too many exercise and too many sets in such a program. You want a brief and to the point workout, which can be very intense, when approached the correct way. Also want enough time between workouts to allow recovery time, for the CNS. A full body workout is generally set up for 2 or 3 days a week, never more. That would be self defeating.
The old Bill Star full body work (several versions of 3 to 5 exercise each workout) which was know as 5X5's gave some pretty good results in a shorter length of time. Though Bill Star wan not the first, by any means, to come up with this style of program. If you do more reps, 10-12 with a more moderate weight for example, than decrease the set to 3-4 per workout. BB'ing is not about how many sets for a body area, but how many total reps are done. Sets only break down the total amount of reps into a more manageable number. Quite a different between 5X5=25 reps and doing 25 straight reps in one set.
The original 20 rep breathing squat program was one of the first. Where pullovers (straight/bent arm) were included after the set of squats. This is a brutal way to train, but added a lot of muscle to men over the years. I made some of my best gains with 20-25 rep breathing squat and the bent arm pullover & press.....he only exercise I did in a workout.
A simple full body workout would be...with 5X5's in mind. Also keeping in mind a brief, but intense, workout.
squats
BB rows
Bench
Up-right row (EZ bar..if handy)
If insecurity's reach a point that you must to do triceps or biceps (or both) and/or calves, than might suggest 2-3 sets max. And if you could do those arm exercise a few hours after the main workout, so much the better.
Good Luck.