This is interesting.
"In a pronated position during an arm curl, the brachialis shows the highest EMG activity, when compared to the brachioradialis and biceps brachii. It is not that the brachialis' EMG activity changes because of various arm positions, but instead, the EMG activity of the biceps and brachioradialis decreases because of this mechanically, disadvantageous position of these two muscles. (Kendall, et. al, 1993, pg 268.)" Quoted from 'Effective Strength Trainining' by Douglas Brooks